The macrocycle of leinamycin imparts hydrolytic stability to the thiol-sensing 1,2-dithiolan-3-one 1-oxide unit of the natural product.

نویسندگان

  • Santhosh Sivaramakrishnan
  • Leonid Breydo
  • Daekyu Sun
  • Kent S Gates
چکیده

Reaction of cellular thiols with the 1,2-dithiolan-3-one 1-oxide moiety of leinamycin triggers the generation of DNA-damaging reactive intermediates. Studies with small, synthetic analogues of leinamycin reveal that the macrocyclic portion of the natural product imparts remarkable hydrolytic stability to the 1,2-dithiolan-3-one 1-oxide heterocycle without substantially compromising its thiol-sensing property.

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عنوان ژورنال:
  • Bioorganic & medicinal chemistry letters

دوره 22 11  شماره 

صفحات  -

تاریخ انتشار 2012